Aluminium (aluminum in American and Canadian English) i s a chemical element with the symbol Al and atomic number 13. It is a silvery-white, soft, non-magnetic and ductile metal in the boron group. By mass, aluminium makes up about 8% of the Earth's crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below. The chief ore of aluminium is bauxite. Aluminium metal is highly reactive, such that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals.
Aluminium is remarkable for its low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the aerospace industry[8] and important in transportation and building industries, such as building facades and window frames. The oxides and sulfates are the most useful compounds of aluminium. Despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts' abundance, the potential for a biological role for them is of continuing interest, and studies continue.
Aluminium is the most widely used non-ferrous metal. The global production of aluminium in 2016 was 58.8 million metric tons. It exceeded that of any other metal except iron (1,231 million metric tons). Aluminium is almost always alloyed, which markedly improves its mechanical properties, especially when tempered. For example, the common aluminium foils and beverage cans are alloys of 92% to 99% aluminium.[121] The main alloying agents are copper, zinc, magnesium, manganese, and silicon (e.g., duralumin) with the levels of other metals in a few percent by weight.
The major uses for aluminium metal are in:
Transportation
(automobiles, aircraft, trucks, railway cars, marine vessels, bicycles, spacecraft, etc.). Aluminium is used because of its low density;
Packaging (cans, foil, frame etc.). Aluminium is used because it is non-toxic, non-adsorptive, and splinter-proof;
Building and construction (windows, doors, siding, building wire, sheathing, roofing, etc.). Since steel is cheaper, aluminium is used when lightness, corrosion resistance, or engineering features are important;
Electricity-related uses (conductor alloys, motors and generators, transformers, capacitors, etc.). Aluminium is used because it is relatively cheap, highly conductive, has adequate mechanical strength and low density, and resists corrosion;
A wide range of household items, from cooking utensils to furniture. Low density, good appearance, ease of fabrication, and durability are the key factors of aluminium usage;
Machinery and equipment (processing equipment, pipes, tools). Aluminium is used because of its corrosion resistance, non-pyrophoricity, and mechanical strength.
Compounds
The great majority (about 90%) of aluminium oxide is converted
to metallic aluminium.[113] Being a very hard material (Mohs hardness 9),
alumina is widely used as an abrasive;[125] being extraordinarily chemically inert,
it is useful in highly reactive environments such as high pressure sodium lamps.
Aluminium oxide is commonly used as a catalyst for industrial processes;
e.g. the Claus process to convert hydrogen sulfide to sulfur in refineries and to alkylate amines.[127][128] Many industrial catalysts are supported by alumina, meaning that the expensive catalyst material is dispersed over a surface of the inert alumina.[129] Another principal use is as a drying agent or absorbent.[113][130]
Laser deposition of alumina on a substrate
Several sulfates of aluminium have industrial and commercial application. A
luminium sulfate (in its hydrate form) is produced on the annual scale
of several millions of metric tons.[131] About two-thirds is consumed in water treatment.
The next major application is in the manufacture of paper.
It is also used as a mordant in dyeing, in pickling seeds, deodorizing of mineral oils,
in leather tanning, and in production of other aluminium compounds.
Two kinds of alum, ammonium alum and potassium alum, were formerly used as
mordants and in leather tanning, but their use has significantly declined
following availability of high-purity aluminium sulfate. Anhydrous
aluminium chloride is used as a catalyst in chemical and petrochemical industries,
the dyeing industry, and in synthesis of various inorganic and organic compounds.
Aluminium hydroxychlorides are used in purifying water, in the paper industry,
and as antiperspirants. Sodium aluminate is used in treating water
and as an accelerator of solidification of cement.
Many aluminium compounds have niche applications, for example:
Aluminium acetate in solution is used as an astringent.
Aluminium phosphate is used in the manufacture of glass, ceramic,
pulp and paper products, cosmetics, paints, varnishes, and in dental cement.
Aluminium hydroxide is used as an antacid, and mordant; it is used also in water
purification, the manufacture of glass and ceramics, and in the waterproofing of fabrics.
Lithium aluminium hydride is a powerful reducing agent used in organic chemistry.
Organoaluminiums are used as Lewis acids and cocatalysts.
Methylaluminoxane is a cocatalyst for Ziegler–Natta olefin
polymerization to produce vinyl polymers such as polyethene.
Aqueous aluminium ions (such as aqueous aluminium sulfate)
are used to treat against fish parasites such as Gyrodactylus salaris.[140]
In many vaccines, certain aluminium salts serve as an
immune adjuvant (immune response booster) to allow the protein in the
vaccine to achieve sufficient potency as an immune stimulant.